The code I provided is a sample to show you how to get what you requested. You need to apply it to your current code. I imagine you have a loop setup already that goes through column F. If you don't, here is some more example code:
Sub tgr()
Dim rngF As Range
Dim FCell As Range
Dim arrCodes() As Variant
Dim CodeIndex As Long
Set rngF = Range("F1", Cells(Rows.Count, "F").End(xlUp))
ReDim arrCodes(1 To rngF.Rows.Count)
For Each FCell In rngF.Cells
CodeIndex = CodeIndex + 1
arrCodes(CodeIndex) = Split(Trim(FCell.Text), " ")(0)
Next FCell
MsgBox Join(arrCodes, Chr(10))
Set rngF = Nothing
Set FCell = Nothing
Erase arrCodes
End Sub
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