Thanks Kyle. I'll give it a go 
Here's where I have reached so far...
Option Explicit
Private Const strURL = "http://www.rba.gov.au/statistics/hist-exchange-rates/2010-2013.xls"
Private Declare Function URLDownloadToFile Lib "urlmon" Alias _
"URLDownloadToFileA" (ByVal pCaller As Long, ByVal szURL As String, ByVal _
szFileName As String, ByVal dwReserved As Long, ByVal lpfnCB As Long) As Long
Public Sub DownloadExcel_Read_Kill()
Dim strDownloadFullPath As String
Dim wbExcelDownload As Workbook
Dim ext As String
Dim buf As Variant
Dim ret As Long
Dim lngFileName As Long
' determine file extension
buf = Split(strURL, ".")
ext = "." & buf(UBound(buf))
buf = vbNull
' set download file path & name
lngFileName = Now()
strDownloadFullPath = Environ("Temp") & "\" & lngFileName & ext
' download file
ret = URLDownloadToFile(0, strURL, strDownloadFullPath, 0, 0)
' check if file downloaded successfully
If Not ret = 0 Then
MsgBox "Download failed", vbCritical, "ERROR"
Exit Sub
End If
' file open & read
Application.ScreenUpdating = False
Set wbExcelDownload = Workbooks.Open(strDownloadFullPath)
Debug.Print "To insert read code here"
' file close & kill
With wbExcelDownload
.Saved = True
.ChangeFileAccess Mode:=xlReadOnly
Kill .FullName
.Close SaveChanges:=False
End With
Application.ScreenUpdating = True
End Sub
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