I typically use a set of standard commands for opening an Word application instance and later closing it:
Dim RApath As String
Dim wrdApp As Object
Application.ScreenUpdating = False
Set wrdApp = CreateObject("Word.Application")
Set RArng = Sheets("Required RA").Columns("C:C").SpecialCells(xlCellTypeFormulas, 2)
Set PATHS = Sheets("RA Paths").Range("A3:B" & Rows.Count).SpecialCells(xlCellTypeConstants)
RApath = Application.WorksheetFunction.VLookup("C:\", PATHS, 2, 0)
With wrdApp.documents.Open(RApath)
.PrintOut Background:=False, Copies:=1
.Close False
End With
wrdApp.Quit False
Set wrdApp = Nothing
Set RArng = Nothing
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