For this to work, move the values down to start at A2, put "Score" in A1. Put "Rank" in B1, then this formula in B2, copied down:
=IF($A2=0, "", RANK($A2,$A$2:$A$100)&MID("thstndrdth", MIN(9, 2 * RIGHT(RANK(A2,$A$2:$A$100))*(MOD(RANK(A2,$A$2:$A$100)-11, 100) > 2) + 1), 2))
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