Hi Madams, welcome to the forum.
Rather than using a convoluted Data Validation formula, perhaps a worksheet change event (macro) would be better suited? This code, which would be added to the code module for the worksheet on which you're entering data, will check column A for any changes as you make them, and determine whether or not the entry is valid. It looks for the three formats you specified above (XX00000, 00000000X and 000000X). You can adjust the code to suit your actual data layout.
This could also be done using Regular Expressions (regex), but I'm not very good at using those just yet.
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