To be honest I'm not an Access-junkie, I have always used MySQL as my DB and either XL/Web as client / front-end... there is an Access forum here with some knowledgable folks who I'm sure would try and help out...
Obviously XL is great for building Charts and for any Chart questions you may have there is a dedicated Charts Forum -- in which lurks Andy Pope, the very well known Chart-Guru (MS Excel MVP -
http://www.andypope.info)
Back to your XL/Access questions...
In this context ADO is essentially just a means by which you can pass SQL queries etc to your DB so you can pretty much run any query you want... ie you can fire any SQL statement from XL just as you would in Access.
If you google VBA/ADO you should find plenty (and I mean plenty) of examples

... here's one quick example taken from VBAXpress:
http://www.vbaexpress.com/kb/getarticle.php?kb_id=889
(note you will need to reference the Microsoft Data Access Object Library in VBEditor (via Tools -> References) - the highest version listed ... if not listed you will need to install MDAC - repeat on each client)
Bookmarks