As with a lot of charting questions, I think that this ends up being more about data layout. If you arrange the data correctly, creating the chart should be easy.
Something like this:
With your data arranged like this, you should be able to select this block, insert scatter chart, and the chart should just about create itself. If Excel gets rows/columns wrong, you may need to click on "switch row/column" or go into the "select data dialog" and manually select the first row as the horizontal axis data.
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